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Recognition of Thymine Attached Cryptand with Adenine Functionalized Amphiphiles: Syntheses and Monolayer Study at the Air-Water Interface
Current Issue
Volume 4, 2017
Issue 1 (February)
Pages: 1-8   |   Vol. 4, No. 1, February 2017   |   Follow on         
Paper in PDF Downloads: 24   Since Aug. 28, 2017 Views: 1214   Since Aug. 28, 2017
Authors
[1]
Bijay Sarkar, Department of Chemistry, IIT Kanpur, Kanpur, India; School of Medicine, University of Maryland Baltimore, Baltimore, USA.
[2]
R. A. Singh, Faculty of Science, Banaras Hindu University, Varanasi, India.
[3]
Tapas Makar, School of Medicine, University of Maryland Baltimore, Baltimore, USA.
[4]
P. K. Bharadwaj, Department of Chemistry, IIT Kanpur, Kanpur, India.
Abstract
Three ligands containing thymine attached through propyl spacer to the N atom(s) of a laterally non-symmetric cryptand (L1-L3) and three 9-alkyladenine (A1-A3, alkyl chain lengths: C18, C20, C22) amphiphiles were synthesized and characterized. Monolayers of the amphiphiles and amphiphiles mixed with thymine-cryptands were studied at the air-water interface on a Langmuir Blodgett Trough; molecular recognition between the amphiphiles and thymine-cryptands at the air-water interface was demonstrated from the change in the patterns of the pressure-area isotherms. Multi-layer Langmuir-Blodgett (LB) films were deposited on quartz plates and studied microscopically.
Keywords
Cryptand, Amphiphile, Molecular Recognition, Monolayers, Langmuir-Blodgett Film, Adenine, Thymine, Thin Film
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