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Recognition of Thymine Attached Cryptand with Adenine Functionalized Amphiphiles: Syntheses and Monolayer Study at the Air-Water Interface
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Volume 4, 2017
Issue 1 (February)
Pages: 1-8   |   Vol. 4, No. 1, February 2017   |   Follow on         
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Bijay Sarkar, Department of Chemistry, IIT Kanpur, Kanpur, India; School of Medicine, University of Maryland Baltimore, Baltimore, USA.
R. A. Singh, Faculty of Science, Banaras Hindu University, Varanasi, India.
Tapas Makar, School of Medicine, University of Maryland Baltimore, Baltimore, USA.
P. K. Bharadwaj, Department of Chemistry, IIT Kanpur, Kanpur, India.
Three ligands containing thymine attached through propyl spacer to the N atom(s) of a laterally non-symmetric cryptand (L1-L3) and three 9-alkyladenine (A1-A3, alkyl chain lengths: C18, C20, C22) amphiphiles were synthesized and characterized. Monolayers of the amphiphiles and amphiphiles mixed with thymine-cryptands were studied at the air-water interface on a Langmuir Blodgett Trough; molecular recognition between the amphiphiles and thymine-cryptands at the air-water interface was demonstrated from the change in the patterns of the pressure-area isotherms. Multi-layer Langmuir-Blodgett (LB) films were deposited on quartz plates and studied microscopically.
Cryptand, Amphiphile, Molecular Recognition, Monolayers, Langmuir-Blodgett Film, Adenine, Thymine, Thin Film
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