Effect of Nickel and Iron Addition on the Structure and Mechanical Properties of Tin Bronze (Cu-10wt%Sn)
[1]
Kingsley Chidi Nnakwo, Department of Metallurgical and Materials Engineering, Nnamdi Azikiwe University, Awka, Nigeria.
[2]
Ifeanacho Uchenna Okeke, Department of Metallurgical and Materials Engineering, Nnamdi Azikiwe University, Awka, Nigeria.
[3]
Jerome Ugwu Odo, Department of Metallurgical and Materials Engineering, Nnamdi Azikiwe University, Awka, Nigeria.
The main objective of this research was to study the effect of nickel and iron addition on the structure and mechanical properties of tin bronze (Cu-10%wt.Sn). The nickel and iron content was varied at concentration of 0.2, 0.4, 0.6, 0.8 and 1%wt respectively. The alloys samples were produced using permanent die casting technique and machined to the required dimension for the mechanical tests and structural analysis. Mechanical properties such as percentage elongation, ultimate tensile strength, brinell hardness and impact strength were conducted using JPL tensile strength tester (Model: 130812), dynamic hardness tester and impact testing machine respectively. The structural analysis was conducted using an optical metallurgical microscope (model: L2003A) and scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS). Structural analysis of the control sample revealed the presence of α-phase and dendrite of intermetallic compound. Fine and evenly distributed intermetallic phases were indicated in the alloy doped with nickel and iron respectively. Results of the mechanical properties indicated that addition of nickel and iron significantly improved the percentage elongation, ultimate tensile strength, hardness and impact strength of tin bronze. Maximum percentage elongation and impact strength of 36.5% and 34J respectively were obtained by the sample containing 0.2%wt iron content while optimum ultimate tensile strength and hardness values of 300MPa and 275MPa respectively were obtained by the sample containing 1%wt zinc content.
Bronze, Mechanical Properties, Ductility, Structure, Intermetallic Phases
[1]
Stanislov S. N., Irina B. M. and Oleg D. N. (2009) Handbook of Non-Ferrous Metal Powders. Page: 331-368.
[2]
Mao T., Bian X., Xue X., Zhang Y., Guo J. and Sun B. (2007) Correlation between Viscosity of Molten Cu–Sn Alloys and Phase Diagram. Physica B. Vol: 387, pp: 1–5.
[3]
Nagy E., Kristaly F., Gyenes A. and Gacsi Z. (2015) Investigation of Intermetallic Compounds in Sn-Cu-Ni Lead-Free Solders. Archives of Metallurgy and Materials, Volume 60, Issue 2, pp. 1511-1515.
[4]
Ketut G. S. I., Soekrisno R. and Made M. I. and Suyitno (2011) The Effect of Annealing Temperature on Damping Capacity of the Bronze 20%Sn Alloy. International Journal of Mechanical and Mechatronics Engineering IJMME-IJENS, Vol: 11 No: 04, pp. 1-5.
[5]
Favstov Y. K., Zhravel L. V. and Kochetkova L. P. (2003) Structure and Damping Capacity of Br022 Bell Bronze,” Journal Metal science and Heat treatment, vol. 45, pp. 449-451.
[6]
Eggenschwiler C. E. (2001) Effect of Antimony on the Mechanical Properties of A Bearing Bronze (Cu 80: Sn 10: Pb 10). Bureau of Standards Journal of Research, Vol. 8, pp. 625-634.
[7]
Martorano M. A. and Capocchi J. D. T (2000) Dendrite Structure Control in Directionally Solidified Bronze Castings. International Journal of Cast Metals Res., Vol. 13, pp. 49-57.
[8]
Marcelo A. M. and José D. T. C. (2000) Effects of processing variables on the micro segregation of directionally cast samples. Metallurgical and Materials Transactions A. Volume 31, Issue 12, pp 3137-3148.
[9]
Kumoto E. A., Alhadeff R. O. and Martorano M. A. (2002) Microsegregation and Dendrite Arm Coarsening in Tin Bronze. Materials Science and Technology. Vol. 18, pp. 1001-1006.
[10]
Ilangovan S. and Sellamuthu R. (2013) Effects of Tin on Hardness, Wear Rate and Coefficient of Friction of Cast Cu-Ni-Sn Alloys. Journal of Engineering Science and Technology. Vol. 8, No. 1, pp. 34 – 43.
[11]
Krivtsova O., Ibatov M., Tolkushkin A., Talmazan V., Amanzholov Z. (2016) Investigation of ECAP on Microstructure and Mechanical Properties of Bronze at Different Temperatures. Journal of Civil Engineering and Construction, 5(2): 83-89.
[12]
Nadolski M. (2017) The Evaluation of Mechanical Properties of High-tin Bronzes. Archives of Foundry Engineering, 17(1): 127-130.
[13]
Martyushev N., Semenkov I. V. and Petrenko Y. N. (2014) Structure and Properties of Leaded Tin Bronze under Different Crystallization Conditions", Advanced Materials Research, Vol. 872, pp. 89-93.
[14]
Sergejevs A., Kromanis A., Ozolins J., Gerins E. (2016) Influence of Casting Velocity on Mechanical Properties and Macro-Structure of Tin Bronzes, Key Engineering Materials, Vol. 674, pp. 81-87.
[15]
Kexing S., Yanjun Z., Peifeng Z., Yanmin Z. and Ning B. (2013) Cu-10Sn-4Ni-3Pb Alloy Prepared by Crystallization Under Pressure: An Experimental Study. Acta Metall. Sin. (Engl. Lett.) Vol. 26 No. 2 pp. 199-205.