Welcome to Open Science
Contact Us
Home Books Journals Submission Open Science Join Us News
Mechanical Properties of Alkali-Silica Reaction Gel Measured by Nanoindenter
Current Issue
Volume 2, 2015
Issue 5 (September)
Pages: 121-124   |   Vol. 2, No. 5, September 2015   |   Follow on         
Paper in PDF Downloads: 70   Since Sep. 29, 2015 Views: 1655   Since Sep. 29, 2015
Authors
[1]
Kai-Wei Liu, Texas A&M Transportation Institute, Texas A&M University, College Station, Texas, USA.
[2]
Aishwarya Baranikumar, HVJ Associates, Inc., Austin, Texas, USA.
[3]
Zachary Grasley, Department of Civil Engineering, Texas A&M University, College Station, Texas, USA.
[4]
Anol K. Mukhopadhyay, Texas A&M Transportation Institute, Texas A&M University, College Station, Texas, USA.
Abstract
The mechanical properties, particularly the elastic modulus and hardness of alkali-silica reaction (ASR) gel are measured at the microscopic scale by nanoindentation. The ASR gels are simulated in the laboratory by reacting amorphous silica (i.e., borosilicate glass) with different alkali hydroxide solutions. The measured elastic modulus of gel, formed by reacting borosilicate glass in sodium hydroxide solution was found to have a mean value of 2.96 GPa, while the gel formed from a combination of sodium hydroxide, potassium hydroxide, and calcium hydroxide solution has the mean modulus of 5.17 GPa. The results show that the presence of potassium and calcium alkalis increases the elastic modulus and hardness of the gel. A student’s t-test performed on the results confirmed the statistical significance.
Keywords
Alkali-Silica Reaction, Mechanical Property, Nanoindentation
Reference
[1]
Jones AEK, Clark LA. The effect of ASR on the properties of concrete and the implications for assessment. Eng Struct 1997; 20(9): 785-91.
[2]
Hou X, Struble LJ, Kirkpatrick RJ. Formation of ASR gel and the roles of C-S-H and portlandite. Cem Concr Res 2004; 34(9): 1683-96.
[3]
Ulm FJ, Coussy O, Li K, Larive C. Thermo-chemo-mechanics of ASR expansion in concrete structures. J Eng Mech 2000; 126(3): 233-42.
[4]
Baz˘ant ZP, Steffens A. Mathematical model for kinetics of alkali-silica reaction in concrete. Cem Concr Res 2000; 30(3): 419-28.
[5]
Capra B, Sellier A. Orthotropic modelling of alkali-aggregate reaction in concrete structures: numerical simulations. Mech Mater 2003; 35(8): 817-30.
[6]
Farage MCR, Alves JLD, Fairbairn EMR. Macroscopic model of concrete subjected to alkali–aggregate reaction. Cem Concr Res 2004; 34(3): 495-505.
[7]
Comi C, Fedele R, Perego U. A chemo-thermo-damage model for the analysis of concrete dams affected by alkali-silica reaction. Mech Mater 2009; 41(3): 210-30.
[8]
Grimal E, Sellier A, Multon S, Le Pape Y, Bourdaro E. Concrete modelling for expertise of structures affected by alkali aggregate reaction. Cem Concr Res 2010; 40(4): 502-7.
[9]
Pesavento F, Gawin D, Wyrzykowski M, Schrefler BA, Simoni L. Modeling alkali-silica reaction in non-isothermal, partially saturated cement based materials. Comput Methods Appl Mech Eng 2012; 225-228: 95-115.
[10]
A. C. Fischer-Cripps, Nanoindentation, Springer-Verlag, New York, 2002.
[11]
Liu KW, Mukhopadhyay A. Alkali-silica reaction in a form of chemical shrinkage. Civil Eng Arch 2014; 2(6): 235-44.
[12]
Liu KW, Mukhopadhyay A. A kinetic-based ASR aggregate classification system. Const Build Mat 2014; 68: 525-34.
[13]
Liu KW, Mukhopadhyay A. Accelerated concrete-cylinder test for alkali-silica reaction.” ASTM J Testing Eval 2015; 44(3): 1-10.
[14]
Velez K, Maximilien S, Damidot D, Fantozzi G, Sorrentino F. Determination by nanoindentation of elastic modulus and hardness of pure constituents of Portland cement clinker. Cem Concr Res 2000; 31(4): 555-61.
[15]
Murtagh MJ, Graham EK, Pantano CG. Elastic moduli of silica gels prepared with tetraethoxysilane. J Am Ceram Soc 1986; 69(11): 775-9.
[16]
Adachi T, Sakka S. Dependence of the elastic moduli of porous silica gel prepared by the sol-gel method on heat-treatment. J Mater Sci 1990; 25(11): 4732-7.
[17]
Struble LJ. Swell and other properties of synthetic alkali silica gels. Purdue University, Centre de Recherche Interuniversitaire sur le Beton (CRIB, Laval and Sherbrooke Universities), Quebec, Canada, 1979, pp. 150.
[18]
Knudsen T, Thaulow N. Quantitative microanalyses of alkali- silica gel in concrete. Cem Concr Res 1975; 5: 443-54.
[19]
Gaboriaud F, Chaumont D, Nonat A, Craievich A. Fractal structure of basic silica gels with low Ca content. J. Appl. Crystallogr 2000; 33: 597-9.
[20]
Phair JW, Tkachev SN, Manghnani MH, Livingston RA. Elastic and structural properties of alkaline-calcium silica hydrogels. J Mat Res 2005; 20(2): 344-9.
[21]
Struble L, Diamond S. Unstable swelling behaviour of alkali silica gels. Cem Conc Res 1981; 11: 611-7.
Open Science Scholarly Journals
Open Science is a peer-reviewed platform, the journals of which cover a wide range of academic disciplines and serve the world's research and scholarly communities. Upon acceptance, Open Science Journals will be immediately and permanently free for everyone to read and download.
CONTACT US
Office Address:
228 Park Ave., S#45956, New York, NY 10003
Phone: +(001)(347)535 0661
E-mail:
LET'S GET IN TOUCH
Name
E-mail
Subject
Message
SEND MASSAGE
Copyright © 2013-, Open Science Publishers - All Rights Reserved