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Heavy Metals Speciation of Soil from Automobile Mechanic Workshops in Oshogbo Metropolis, South Western Nigeria
Current Issue
Volume 3, 2018
Issue 1 (January)
Pages: 1-10   |   Vol. 3, No. 1, January 2018   |   Follow on         
Paper in PDF Downloads: 68   Since Apr. 9, 2018 Views: 1168   Since Apr. 9, 2018
Authors
[1]
Olusola Adelowotan, Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria.
[2]
Iyabo Oluremi Olabanji, Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria.
[3]
Oladotun Wasiu Makinde, Centre for Energy Research and Development, Obafemi Awolowo University, Ile-Ife, Nigeria.
[4]
Emmanuel Ayodele Oluyemi, Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria.
Abstract
Heavy metals speciation of soils around automobile mechanic workshops in Oshogbo metropolis were carried out in order to access the effects of indiscriminate disposal of used oil and scraps on the soil environment. Soil samples were collected at two different depths of 0–15 cm and 15–30 cm from four different automobile workshops. The air–dried samples were pulverized and subjected to four–stage sequential extraction procedure for the determination of six heavy metals in the sample. The speciation results at 0–15 cm soil depth indicated significant amount of Cd and Zn were associated with the exchangeable and bound to carbonate fraction. Cu and Pb were prevalently held in the Fe–Mn oxide fraction. At 15–30 cm soil depth, predominate form of Cu, Pb and Zn existed in the Fe–Mn oxide fraction, and significant amount of Cd was associated with organic matter fraction. Cr and Ni were prevalently held in the residual fraction at both depths. The study concluded that the soils at the four auto-mobile mechanic workshops were polluted.
Keywords
Heavy Metals, Speciation, Contamination Index, Geoaccumulation Index
Reference
[1]
Adekola, F. A., Abdus-Salam, N., Bale, R. B., and Oladeji, I O. (2010). Sequential extraction of trace metals and particle size distribution studies of Kainji lake sediment, Nigeria. Chemical Speciation and Bioavailability, 22 (1) pp 43-49.
[2]
Adelekan, B. A., and Abegunde, K. D. (2011). Heavy metals contamination of soil and groundwater at automobile mechanic villages in Ibadan, Nigeria. International Journal of the Physical Sciences Vol. 6 (5), pp. 1045-1058.
[3]
Akporido, S. O. and Asagba, S. O. (2013). Quality Characteristics of Soil Close to the Benin River in the Vicinity of a Lubricating Oil Producing Factory, Koko, Nigeria. International Journal of Soil Science, 8: 1-16.
[4]
Akpoveta, O. V., Osakwe, S. A., Okoh, B. E., and Otuya, B. O. (2010). Physicochemical Characteristics and Levels of Some Heavy Metals in Soils around Metal Scrap Dumps in Some Parts of Delta State, Nigeria. J. Appl. Sci. Environ. Manage., 14 (4) 57-60.
[5]
Asaah, A. V., Abimbola, A. F., and Suh, C. E. (2005). Heavy metal concentrations and distribution in surface soils of the Bassa Industrial Zone 1, Doula, Cameroon. The Arabian Journal for Science and Engineering, Volume 31, Number 2 A. pp 147-158
[6]
Atuanya, E. J. (1987). Effect of oil pollution on physical and chemical properties of soil: a case study of waste oil contaminated delta soil in Bendel State, Nigeria. Journal of Applied Science, 55; 155-176.
[7]
Banerjee, A. D. K. (2003). Heavy metal levels and solid phase speciation in street dusts of Delhi, India. Environ. Pollut., 123, 95-105.
[8]
Burger, J. and Gochfeld, M. (2000). Effects of lead on birds (Laridae): A review of laboratory and field studies. J. Toxicol. Environ. Health, 3: 59-78. PMID: 10834076.
[9]
Clevenger, T. E., (1990). Water, Air, Soil Pollut., 50, 241.
[10]
Filgueiras, A. V., Lavilla, I., and Bendicho, C., (2002). Chemical sequential extraction for metal partitioning in environmental solid samples. JEM tutorial review.
[11]
Eisler, R., (1988). Lead Hazards to Fish, Wildlife and Invertebrates: A Synoptic Review. US Fish and Wildlife Service, Washington, DC.
[12]
Foo, C. Y., Rosli, M. Y., Tea, S. S., (2002). Modeling and Simulation of used Lubricant Oil Re-refining Process. 2nd World Engineering Congress Sarawak, Malaysia.
[13]
Gao, X., Chen, S., Long, A. (2008). Chemical speciation of 12 metals in surface sediments from the northern South China Sea under natural grain size. Baseline/Marine Pollut. Bull., 56, 770-797.
[14]
Godt J, Scheidig F, Grosse-Siestrup C, Esche V, Brandenburg P, Reich A and Groneberg DA (2006). The toxicity of cadmium and resulting hazards for human health, J. Occupational Med. and Toxicol., 1 (22), 1-6.
[15]
Haghiri, F., (1974). Plant uptake of cadmium as influenced by cation exchange capacity, organic matter, zinc and soil tem¬perature. J Environ. Qual... 3, 180.
[16]
Horsfall, M. (Jnr.) and Spiff, A. (2005). Speciation and bioavailability of heavy metals in sediment of Diobu River, Port Harcourt, Nigeria. Europ. J. Sci. Res. 6 (3): 20-36.
[17]
Huu, H. H., Rudy, S., and Damme, A. V., (2010). Distribution and contamination status of heavy metals in estuarine sediments near Cau Ong harbor, Ha Long Bay, Vietnam. Geol. Belgica, 13 (1-2): 37-47.
[18]
Ikem, A., Egiebog, N. O. and Nyavor, K. (2003). Trace Elements in water, fish and sediment from Tuskegee Lake, Southeastern USA. Water, Air Soil Pollut., 149: 51-75.
[19]
Irwin, R. J., VanMouwerik, M., Stevens, L., Seese, M. D., and Basham W., (1997). Environmental Contaminants Encyclopedia. National Park Service, Water Resources Division, Fort Collins, Colorado.
[20]
Lena, Q. M., and Gade N. R., (1997). Chemical Fractionation of Cadmium, Copper, Nickel, and Zinc in Contaminated Soils. Journal of Environmental Quality Volume 26, (1): 259-264.
[21]
Marin B., Valladon M., Polve M. and Monaco A., (1997). Anal. Chim. Acta, Vol. 342, p 91
[22]
Mediolla, L. L., Domingues M. C. D. and Sandoval M. R. G., (2008). Environmental Assessment of active Tailings pile in the State of Mexico (Central Mexico). Res. J. Environ. Sci., 2 (3): 197-208.
[23]
Nwachukwu M. A.; Feng H.; Alinnor J. (2010). Assessment of heavy metal pollution in soil and their implications within and around mechanic villages. Int. J. Environ. Sci. Tech., 7 (2), 347-358
[24]
Odjegba, V. J., and Sadiq, A. O. (2002). Effect of spent engine oil on the growth parameters, chlorophyll and protein levels of Amaranthus hybridus. The Environmentalist, 22; 23-28.
[25]
Okunola O. J., Uzairu A., Gimba C. E. and Kagbu J. A. (2011). Geochemical Partitioning of Heavy Metals in Roadside Surface Soils of Different Grain Size along Major Roads in Kano Metropolis, Nigeria. British Journal of Applied Science & Technology 1 (3): 94-115.
[26]
Pickering, W. F., (1986). Metal ion speciation-soils and sediments. Ore Geol. Rev., 1: 83-146.
[27]
Ramos, L., L. M. Hernandez, and M. J. Gonzalez. (1994). Sequential fractionation of copper, lead, cadmium and zinc in soils from or near Donana National Park. J. Environ. Qual. 23: 50-57.
[28]
Tessier, A., Campbell, P. G. C. and Bisson M. (1980). Trace metal speciation in the Yamaska and St. Francois Rivers (Quebec). Can. J. Earth Sci. 17: W-105.
[29]
Tamunobereton-ari I., Omubo-Pepple V. B. and Uko E. D. (2011). Heavy Metal Speciation in contaminated Soils of an abandoned hydrocarbon exploration field camp and Workshop site in part of the Niger delta, Nigeria. J. Basic. Appl. Sci. Res., 1 (6) 456-463.
[30]
Tijani, M. N. and S. Onodera, (2009). Hydro geochemical Assessment of metals contaminationin an urban drainage system: A case study of Osogbo Township, SW-Nigeria. J. Water Resource and Protection, 3: 164-173.
[31]
Shacklette, H. T., and Boerngen J. G. (1984). Element concentrations in soils and other surficial materials of the conterminous United States. U.S. Geol. Survey Professional Paper 1270
[32]
Ure, A. M., Quevauviller, P. H., Muntau, H., Griepink, B., (1992). EUR report, Commission of the European Communities Brussels, EUR 14763.
[33]
Weber, D. N.; Dingel, W. M.; Panos, J. H. and Steinpreis, R. E. (1997). Alterations in neurobehavioral responses in fishes exposed to lead and lead chelating agents. Am. Zool. 37: 354362.
[34]
Yobouet, Y. A., Adouby K., Trokourey A. and Yao B. (2010). Cadmium, Copper, Lead and Zinc speciation in contaminated soils. International Journal of Engineering Science and Technology Vol. 2 (5), 802-812
[35]
Yong, R. N; Mohammed A. M. O and Warkentin B. P (1992). Principles of contaminant transport in soils. Elsevier Science Publishers, Amsterdam, pp 258.
[36]
Yusuf, K. A., (2007). Sequential Extraction of Lead, Copper, Cadmium and Zinc in Soils near Ojota Waste Site. Journal of Agronomy, 6: 331-337.
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