Complexes of Schiff Bases Derived from 2-Hydroxyaldehyde and Propane-1,2-Diamine: Synthesis, Characterization and Antibacterial Screening
[1]
Mohammad Nasir Uddin, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh.
[2]
Didarul Alam Chowdhury, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh.
[3]
Md. Moniruzzman Rony, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh.
Three Schiff base ligands have been derived by the condensation of o-hydroxyaldehydes i.e. salicylaldehyde, o-hydroxyacetophenone and o-hydroxypropiophenone with propane-1,2-diamine. Metal complexes of Fe3+, Ni2+, Cd2+ have been synthesized using the prepared Schiff bases and characterized on the basis of metal analysis, spectral (IR, UV-vis, 1H NMR), magnetic, conductance analysis. Based on these analytical data geometry of the complexes has been proposed. Antibacterial activity of the prepared complexes was investigated and some of the prepared complexes are supposed to be moderately effective against selected human pathogenic bacteria.
Schiff Base Ligand, Fe3+, Ni2+, Cd2+ Complexes, Propane-1,2-Diamine, 2-Hydroxyaldehyde
[1]
Yoon T. P. and E.N. Jacobsen, Science, 299, 1691, 2003.
[2]
Morteza Montazerozohori, Maryam Sedighipoor and Shiva Joohari, Electrochemical Behavior of bis((E) 3-(2-Nitrophenyl) Allylidene)Propane-1,2-Diamine as a New Schiff Base and Some Its New XII Group Complexes Int. J. Electrochem. Sci., 7 (2012) 77 – 88
[3]
Atmaram. K. Mapari and Kiran. V. Mangaonkar Synthesis, Characterization and Antimicrobial Activity of Mixed Schiff Base Ligand Complexes of Transition Metal(II) ions. Int.J. ChemTech Res.2011,3(1), 477-482
[4]
Didarul Alam Chowdhury, Mohammad Nasir Uddin and Farhana Hoque Dioxouranium(VI) Complexes of Some Monovalent Bidentate Schiff Base Ligands Derived from Aniline, CMU. J. Nat. Sci. (2011) Vol. 10(2), 261-268
[5]
Didarul A. Chowdhury, Mohammad N. Uddin, and Farhana Hoque, Dioxouranium(VI) Complexes of Some Bivalent Tridentate Schiff-base Ligands Containing ONS Donor Set, Chiang Mai J. Sci. 2010; 37(3) : 443-450
[6]
Didarul A. Chowdhury, Mohammad N. Uddin and Md. Akter H. Sarker, Synthesis and Characterization of Dioxo-uranium(VI) Complexes of Some Aroylhydrazines and Their Schiff Bases With Acetone, Chiang Mai J. Sci. 2008; 35(3) : 483-494
[7]
D. A. Chowdhury, M. N. Uddin and G. K. Chowdhury, Synthesis and characterization of some dioxomolybdenum(VI) complexes of schiff bases with ONNO donor ligands, The Chitt. Uni. J. of Sci. 30: 1. 85-88 2006.
[8]
M. Mokhles and Abd-Elzaher, J. Chin. Chem. Soc-Taip., 48, 153, 2001
[9]
H. Kokosal, M. Dolaz, M. Tumer and S. Serin, Synth. Inorg. Met. Org.Chem., 31, 1141, 2001
[10]
Mohammad Nasir Uddin, D A Chowdhury, Kamrul Hossain, Titanium(IV) Complexes of Unsymmetrical Schiff Bases Derived from Ethylenediamine and o-Hydroxyaldehyde/Ketone and Their Anti-microbial Evaluation, Journal of the Chinese Chemical Society, 59: 12. 1520-1527 (2012)
[11]
Canpolat E., Kaya M., J. Coord. Chem., 2004, 57, 1217.
[12]
Mohammad N. Uddin, Didarul A. Chowdhury, Mohammed T. Islam, and Farhana Hoque, Evaluation of biological activity of dioxouranium complexes of some Schiff base and dithiocarbamate ligands, Orbital Elec. J. Chem., Campo Grande, 4(4): 273-287, 2012
[13]
G. G. Mohamed, M. M. Omar, and A. M. Hindy, Turk J Chem.30, 361 – 382, 2006.
