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Ti-Substituted Hydroxylapatite Precipitated in the Presence of Titanium Sulphate: A Novel Photocatalyst?
Current Issue
Volume 6, 2019
Issue 1 (March)
Pages: 1-10   |   Vol. 6, No. 1, March 2019   |   Follow on         
Paper in PDF Downloads: 70   Since Apr. 16, 2019 Views: 1130   Since Apr. 16, 2019
Authors
[1]
Fatemeh Asjadi, Ceramics Institute, Materials and Energy Research Center, Karaj, Iran; Steinmann Institutfür Geologie, Mineralogie und Paläontologie, University of Bonn, Bonn, Germany; Engineering Department, Zanjan University, Zanjan, Iran.
[2]
Thorsten Geisler, Steinmann Institutfür Geologie, Mineralogie und Paläontologie, University of Bonn, Bonn, Germany.
[3]
Ismaeil Salahi, Ceramics Institute, Materials and Energy Research Center, Karaj, Iran.
[4]
Harald Euler, Steinmann Institutfür Geologie, Mineralogie und Paläontologie, University of Bonn, Bonn, Germany.
[5]
Iman Mobasherpour, Ceramics Institute, Materials and Energy Research Center, Karaj, Iran.
Abstract
Hydroxylapatite (HAp) doped with about 10 mol.% Ti (TiHAp) has recently been reported to be successfully synthesized by the co-precipitation method coupled to heat treatment and attracted attention as a novel photocatalyst. The formation of TiHAp was re-investigated using the same method and materials. The synthesis products were analysed by Raman spectroscopy and X-ray diffraction. It is demonstrated that the product obtained by the co-precipitation method is a composite material that consists of nano-crystalline anatase and subordinately perovskite (CaTiO3) along with nano-crystalline, slightly Ca-deficient HAp. It follows that the observed photocatalytical properties of TiHAp obtained by this synthesis method are related to the formation of such a composite material rather than to Ti-doped HAp. The experimentally observed photocatalytical properties of TiHAp samples must thus be related to other product properties (e.g., Ti phase composition, crystallite size, and/or surface state) that are controlled by both the presence of Ti in solution and the synthesis method.
Keywords
Hydroxylapatite, TiHAp, Ca-deficient HAp, Titanium Sulphate, Raman Spectroscopy, X-ray Diffraction
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