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Physico-Chemical, GC-MS Analysis and Cold Saponification of Onion (Allium cepa L.) Seed Oil
Current Issue
Volume 2, 2015
Issue 5 (October)
Pages: 110-115   |   Vol. 2, No. 5, October 2015   |   Follow on         
Paper in PDF Downloads: 130   Since Sep. 19, 2015 Views: 2883   Since Sep. 19, 2015
Authors
[1]
Aliyu Ahmad Warra, Department of Biochemistry, Kebbi State University of Science & Technology, Aliero, Nigeria.
[2]
Fatima Sheshi, Department of Pure and Applied Chemistry, Kebbi State University of Science & Technology, Aliero, Nigeria.
Abstract
The experimental investigation revealed that the hexane extract of onion seed oil has acid value, iodine value, peroxide value, saponification value, relative density and refractive index of 0.03±0.01 mg KOH/g, 129.80±0.21 gI2/100g, 3.00± 0.00 meq H2O2, 203.00±0.71 mg KOH/g, 0.82±0.01 and 1.44±0.00 respectively. The percentage yield was 50.28±0.01%. The colour of the oil was light green. We restricted our GC-MS spectra interpretation to compounds identification, particularly fatty acids and they are identified as palmitic acid, linolelaidic acid, oleic acid, stearic acid, behenic acid, linolenic acid and eicosatetraenoic acid. The pH, foam ability (cm³), total fatty matter, total alkali and percentage chloride of the onion oil soap were 11.03± 0.02, 75.13±0.15 (cm³), 36.66 ± 0.02%, 0.92 ± 0.02% and 0.53 ± 0.15 % respectively. The texture was soft and the colour was lighter green. The results indicated that the hexane extract of the onion seed oil has potential for cosmetic industries.
Keywords
Onion Seeds, Soxhlet Extraction, Physicochemical, GC-MS, Cold Saponification
Reference
[1]
Kumar, KP S., Bhowmik, D, Chiranjib, Biswajit and Tiwar, P Allium cepa: A traditional medicinal herb and its health benefits. J. Chem. Pharaceutical Res. 2010.2(1): 283-291.
[2]
Salina, HF, Rinani, AR., Masniza, SM., and Faeizh, HN. Enzyme assisted aqueous extraction and phenolic antioxidants of onion oil. Int. J. Sci. Environ. Technol. 2013, 2(5): 949 – 955.
[3]
Bello, MO., Olabanji, IO., Abdul-Hammed, M. and Okunade, TD. Characterization of domestic onion wastes and bulb (Allium cepa L.): fatty acids and metal contents. Int. Food Res. J. 2013, 20(5): 2153-2158.
[4]
Yalcin, H and Kavuncuoglu, H. Physical, chemical and bioactive properties of onion (Allium cepa L.) seed and seed oil. J. Appl. Bot. Food Quality. 2014. 87, 87 – 92.
[5]
Pant, KS., Koshla, V., Kumar, D. and Gairola, G. Seed oil content variation in Jatropha curcas L indifferent altitudinal ranges and site conditions in H.P. India. Lyonia.2006, 11(2): 31-34.
[6]
Okolie P, Uaboi-Egbenni PO, Ajekwene AE. Extraction and Quality Evaluation of Sandbox Tree Seed Huracrepitan) Oil. World J. Agric. Sci. 2012.8 (4): 359-365.
[7]
John K Analytical Chemistry for Technicians. 3rd Edn. Lewis Publishers, Kalyan Publisher, New Delhi, India.2003, pp 432-433.
[8]
Bassir, O. Handbook of Practical Biochemistry. Ibadan University Press, Nigeria. 1978.
[9]
Official Methods of Analysis of the Association of Official Analytical Chemists, AOAC, 1998. 16th Edn. Gaithersburg, USA.
[10]
Akpan, UG., Jimoh, A and Mohammed, AD. Extraction, characterization and Modification of Castor seed oil. Leonardo J. Sci. 2006, 8: 43-52.
[11]
NIST GC-MS NIST Library Information Manual. 2012.
[12]
Warra, A. A .The Scienceand Technology of soap Production Utilizing Indigenous Raw Materials. Raw Materials Research and Development Council, Abuja, Nigeria. 2012, p128.
[13]
Roila. A, Salmiah. A, and Razmah, GJ. Properties of sodium soap derived from palm-based dhydroxystearic acid. J. Oil Palm Res. 2001, 13(2): 33-38.
[14]
American Oil Chemists’ Society. AOCS Official Methods and Recommended Practices of the American Oil Chemists’ Society. Washington, DC: AOC Press, 1993.
[15]
Onyegbado, CO, Lyagba, ET, Offor, OJ Solid Soap Production using Plantain Peels as Source of Alkali. J. Appl. Sci. & Environ. Management. 2002, 6(1): 73-77.
[16]
Warra, AA., Wawata, IG., Umar, RA., and Gunu, SY. Soxhlet extraction, Physicochemical Analysis and Cold process saponification of Nigerian Jatropha curcas L. Seed oil. Canadian J. Pure and Appl. Sci. 2012, 6 (1): 1803-180719.
[17]
Nzikou, JM., Mvoula-Tsiéri, M., Pambou-Tobi, NPG.,. Ndangui, CB., Kimbonguila, A. Silou, T., Linder, M. ,Scher, J. and Desobry, S. Proximate Composition And Physico-chemical Characteristics Of Seed And Seed Oil From Terminalia Catappa L And The Kinetics Of Degradation Of The Oil During Heating. Australian J. Basic Appl.Sci, 2010, 4(7): 2039-204714.
[18]
Warra, AA. and Komo, JI. (2014). Fat Quality and Cold Saponification of Shea Nut (Vitellariaparadoxa) Fat Extract. J. Scientific Res. Reports, 3(5): 660-667.
[19]
Warra, AA. Physico-Chemical and GC/MS Analysis of wild Castor (Ricinus communis L.) Seed Oil. Appl. Sci. Reports. 2015, 9(3): 123-128
[20]
Ladan, Z, Okonkwo, EM.,Amupitan, Ladan, EO and Aina B. Physicochemical properties and fatty acid profile of hyptis spicigera seeds oil. Res. J. Appl. Sci. 2010, 5: 123-125.
[21]
Ibrahim, TA and Fagbohun, ED. Physicochemical properties and in vitro antibacterial activity of corchorusolitoriuslinn seed oil. Life Sci. Leaflets. 2011, 15:499-505.
[22]
Warra, AA. Production of Soap from Indigenous Moringa oliefera Lam Seed Oil. J. Raw Materials Res. 2012, 7 (1&2): 26-35.
[23]
Adelaja, J O. Evaluation of mineral constituents and Physico-chemical properties of some oil seed. M.Sc. Industrial Chemistry, University of Ibadan, Ibadan. 2006.
[24]
Akububugwo, IE. And Ugbogu, AE. Physicochemical studies on oils from five selected plant seeds. Pakistan J. Nutrition. 2007, 6: 75-78.
[25]
Ikhuoria, EU., Maliki M. Characterization of Avocado pea (persea americana) and African Pear (Dacryodesadulis) extracts. African J.Biotechnol.2007, 6(7):950-952.
[26]
Nwinuka, NM. and Nwiloh, BI. Physico-chemical Properties and Fatty Acid Composition of Dennettia tripetala Fruit Oil (Pepper Fruit).Nigerian J. Biochem. Molecular Bio. 2009, 24 (1): 42 – 4629.
[27]
Gafar, MK. Itodo, AU. Warra, AA. Wyasu, G. and Salisu, NA. Physicochemical/GC-MS Characteristics of Oil and Soap Produced from Cucumismelo Linn Seed Extracts. Int. J. Modern Anal. Separation Sci. 2013, 2(1): 20-30.
[28]
Oladiji, AT., Shoremekun, KL. And Yakubu, MT. Physicochemical Properties of the Oil from the Fruit of Blighia sapida and Toxicological Evaluation of the Oil-Based Diet in Wistar Rats. J. Medicinal Food .2009, 12 (5): 1127–1135
[29]
Khanzadeh, F., Haddad Khodaparast, MH, Elhami Rad, AH. and Rahmani, F Physiochemical Properties of Gundelia tournefortii L. Seed Oil. J. Agric. Sci. Technol, 2012, 14: 1535-1542.
[30]
Anhwange, BA., Ikyenge, BA., Nyiatagher, DT. Ageh, JT. Chemical Analysis of Citrullus Lanatus (Thunb.), Cucumeropsis Mannii (Naud.) and Telfairia Occidentalis (Hook F.) Seeds Oils. J. Appl. Sci. Res, 2010. 6(3): 265-268.
[31]
National Institute for Standard Technology. Octadecanoic acid. Accessed 14/12/2014 at http://webbook.nist.gov/cgi/cbook.cgi?Name=stearic+acid&Units=SI.
[32]
Park, Y. Conjugated linoleic acid (CLA): Good or bad trans fat?" Journal of Food Composition and Analysis. 2009, 22: 4-12.
[33]
Pub Chem. Elaidic acid. Accessed 12/12/2014 at pubchem.ncbi.nlm.nih.gov/compound/ Elaidic acid.
[34]
Bockisch, M. Fats and Oils Handbook. AOCS Press, Champaign, Illinois. 1998. p58.
[35]
Gunstone, FD The chemistry of oils and fats sources, composition, properties and uses. Blackwell Publishing Ltd, UK. 2004. p54.
[36]
PubChem (2015). Linolenic acid. Accessed 12/8/2015 at pubchem.ncbi.nlm.nih.gov/compound/ Linolenic.
[37]
Rangwala, JA. and Sarasan, G. Synthesis of Medicinal Soap from Non Edible (Jatropha Oil) and Study of its Quality Parameters including Antimicrobial Activity.Res. J. Chem. Sci.2014,4(4), 58-62.
[38]
Mak-Mensah, EE. and Firempong, CK. Chemical characteristics of toilet soap prepared from neem (Azadirachtaindica A. Juss) seed oil. Asian Journal of Plant Science and Research, 2011, 1 (4):1-7.
[39]
Warra, AA Hassan, LG. Gunu, SY and Jega, SA. Cold- Process Synthesis and Propertiesof Soaps Prepared from Different Triacylglycerol Sources. Nigerian J. Basic and Appl. Sci.2010, 18(2): 315-321.
[40]
Warra, AA., Wawata, IG., and Gunu, SY. Chemical analysis and base - Promoted hydrolysis of locally extracted shea nut fat.Chemsearch Journal 2011, 2(1): 12 – 15.
[41]
Mainkar, AR. and Jolly, CI. Evaluation of commercial herbal shampoos. Int. J. Cosmetic Sci. 2000, 22: 385-391.
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